Plastics Juxtaposition Creates Boundary Conduction
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From research in the Netherlands, scientists have discovered a duet of non-conductive plastics, that when pushed together, create a boundary layer that conducts electricity as if metal was suddenly placed there.
The crystalline organic polymers TTF and TCNQ were placed together, and it was found that the materials were held loosely by van der Waals forces ( the method of hydrogen bonding, and the way that oxygen, nitrogen, and other diatomic gasses are formed). TTF and TCNQ are both insulators, and a blended polymer, while not as resistive as the materials taken independently, does weakly conduct.
When the two materials are placed together, a measured 2 nanometer region conducts electricity as though the lattice had changed into metal. This layer could be the start of a new form of conductive plastic transistor, as it has been theorized that what allows the electron passage is a tunnel being formed – much like the way that an IG-MOSFET works. Metal Oxide Semiconductor Field Effect Transistors are the creations that mimic the workings of a vacuum tube more than other types of transistors, and the Insulated Gate variety is an analog to the way a screen grid works in a pentode design.
from New Scientist
The result is that, in the 2-nm gap between the molecules of the two different materials, they can travel freely, allowing current to flow. “Such an electron-hole system is really something new and it may have interesting electronic properties,” Morpurgo says.
Jochen Mannhart at the University of Augsburg in Germany agrees. “You do get exciting things happening at interfaces – physics at interfaces is responsible for the behaviour of semiconductors, for instance.”
But the TTF-TCNQ interface conducts electricity much better than standard semiconductors. “The electron concentration there is an order of magnitude higher,” Mannhart says. “That has the power to create new effects, from magnetism to superconductivity.”
Superconductors are not only cool, the research into them is much of what fuels the idea of power transmission without the huge losses currently incurred. This could change many things over the next few years, similar to the changes that occurred when the original junction transistors were perfected.
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Technorati Tags: conductive organics - crystalline structures - hole movement - electron tunneling

2 Comments
leftystrat
June 15th, 2008
at 8:07pm
I am highly handicapped by my total lack of understanding of physics and chemistry. The minor bit that I did (almost) understand was the very interesting mention of MOSFETs impersonating tubes and the screen grid mimic.
I know this technology was lauded for its tube-like effect on audio, specifically guitars, where we like our amps with tubes. I built an old (but still used) design with a CMOS chip (4049 iirc) to ape a driven tube amp. It was kind of cool but nowhere near the real thing.
Wondering if they ever did any better in this area. I remember reading a tiny blurb where the Navy was working on a tube-on-a-chip but never heard about it again (need to know?). Or are we all just going the modeling route?
Have I sufficiently hijacked this topic yet? :)
the oracle
June 15th, 2008
at 9:59pm
MOSFETs are like tubes in that they tend to become non-linear (distort) by emitting odd-order harmonics (3rd, 5th, 7th, etc) which are judged to be more ‘musical’ by humans. Junction transistors (regular NPN or PNP) have a tendency to emit even order (2nd, 4th, 6th, etc) harmonics when becoming non-linear. This is judged by most people as being ‘bad’ sounding, and decidedly less musical.
Nothing using MOSFETs really sounds exactly like tubes, but in good designs, comes close. You won’t hear this closeness in guitar amps, because the attention is not paid to detail - even in the best designs.
Now if you could get someone like John Iverson, or James Bongiornio (truly great electrical designers, makers of the Electron Kinetics, Sumo, Great American Sound, and SAE series of high quality audio amps) to design a guitar amp, you probably would be hard pressed to tell the difference between it and a great old tube amp. BTW, tubes, for any purpose are getting hard to come by, and are very expensive. Last time I checked, they are made in Russia.
Oh, if you don’t know any of those amp names, ask an audiophile, and be prepared for the long winded explanation of their greatness! (also, Great American Sound was known by the actual amp name Ampzilla)